PennO365 Two-Step Verification information can be found here.
You can reach PennO365 webmail by going here.
Your PennO365 password is the same as your Pennkey password. You can reset your Pennkey/PennO365 password here.
Here are frequently asked questions about Using and Configuring your PennO365 Account.
Lynda.com offers some useful video tutorials for people who are new to O365.
To request assistance, contact your Local Support Provider.